In the present study, a strategic designing of multilayer shield was planned to enhance the multiple reflection phenomenon to achieve maximum absorption properties in microwave frequency (C & X band) range. Multi-layer EMR shields were developed using pure cotton fabric and conductive woven fabrics, incorporated with copper- based & silver-plated hybrid yarn. First of all, single layer fabrics were produced in five variants, nomenclature as L1A (pure cotton) L1B, L1C (copper-based hybrid yarn), LS1B and LS1C (silver plated hybrid yarn). These five variants were used to prepare four sets of double & triple layer fabric. In both double and triple layer composition, L1A fabric (pure cotton) was used as top layer followed by B and C series fabrics, containing copper and silver-plated hybrid yarn. The EMSE performance in C and X band frequency range of single layer, double layer and triple layers in terms of scattering parameters S11(reflectance) & S21 (transmittance) in vertical and horizontal wave polarization was studied. It was found that number of layers, layer composition, orientation of metallic yarn, frequency and EM wave polarization have significant influence on overall electromagnetic shielding effectiveness.