Several approaches have been proposed to determine the optimal storage capacity and dispatch strategy in a power system with high renewable penetration. The deployment of alternatives such as sector coupling and reinforcing interconnections among neighbouring countries may reduce the storage capacity that results cost-effective. We use the model PyPSA-Eur-Sec-30, an open, hourly-resolved, one-node-per-country network of the sector-coupled European energy system to investigate the complex interactions among generation technologies, mainly wind and solar PV, storage technologies in the power system (pumped hydro storage [PHS], batteries, and hydrogen storage), and the additional storage brought to the system by coupling the transport (electric vehicle [EV] batteries) and heating sector (short-term and long-term thermal energy storage). The system configuration is optimised under decreasing CO 2 emissions targets. For the power system, significant storage capacities only emerge for CO 2 emissions reduction higher than 80% of 1990 level in that sector. For 95% CO 2 emissions reduction, battery and hydrogen storage energy capacities equivalent respectively to 1.4 and 19.4 times the average electricity demand result cost-effective. The former cycles daily counterbalancing solar generation while the dispatch pattern of the latter is determined by fluctuations in wind generation. Coupling heating and transport sectors enables deeper CO 2 emissions reductions before the required storage capacities diverge. The EV batteries provided by coupling the transport sector avoid the need for additional stationary electric batteries and large energy capacity of centralised thermal energy storage (CTES) is built to deal with the large seasonal variation in heating demand.