June 16 1984
DOI: 10.1515/9783112501627-006
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Linear Thermal Expansion of SrTiO3

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“…This antiferrodistortive phase transition has been studied by a variety of experimental techniques. Clear anomalies in specific heat [20], thermal conductivity [21], sound velocity [22] and thermal expansion [23] have been observed at T AFD 105 K. The transition does not break inversion symmetry, but the boundaries between tetragonal domains become polar [24,25] deep inside the ordered state. In spite of being widely documented over several decades, the consequences of this phase transition for mobile electrons have been elusive.…”
mentioning
confidence: 94%
“…This antiferrodistortive phase transition has been studied by a variety of experimental techniques. Clear anomalies in specific heat [20], thermal conductivity [21], sound velocity [22] and thermal expansion [23] have been observed at T AFD 105 K. The transition does not break inversion symmetry, but the boundaries between tetragonal domains become polar [24,25] deep inside the ordered state. In spite of being widely documented over several decades, the consequences of this phase transition for mobile electrons have been elusive.…”
mentioning
confidence: 94%
“…Another phase transition occurs at around 30 K, below which the Sr-ions disorder along [111] directions, rendering the structure locally triclinic [29][30][31] . Both transitions are accompanied by changes in mechanical properties [32][33][34][35][36] , as well as in the thermal expansion coefficient of STO 37 and can therefore be related to the signatures at 165 K and 30 K in Fig. 3a.…”
Section: Temperature-dependent Mechanical Propertiesmentioning
confidence: 90%