1996
DOI: 10.1007/bf00129346
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Lipase-catalyzed resolution of primary alcohol containing quaternary chiral carbon

Abstract: 2-Cyano-2-phenyl-I-hexanol containing chiral quatemary carbon was resolved using a lipase. Among various reaction conditions, transesterification reaction (solvent; n-hexane, lipase; Candida cylindracea) gave high selectivity(20/80). Additionally, the selectivity could be improved( 13187) when pyridine( 1%) was used as an additive. The ratios of resolved alcohols were determined by GC and 'H-NMR analysis using Mosher's derivative.

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Cited by 11 publications
(2 citation statements)
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“…3. The equations to find the value of each variable in this map were taken from [15][16][17][18][19]. The constraints to define the final geometry of the exchanger included: • A gas outlet temperature of 100°C ± 2°C • A maximum bank width of 1300 mm (The ducts of the stenter are 750 mm.…”
Section: Methodology To Design the Heat Exchangermentioning
confidence: 99%
See 1 more Smart Citation
“…3. The equations to find the value of each variable in this map were taken from [15][16][17][18][19]. The constraints to define the final geometry of the exchanger included: • A gas outlet temperature of 100°C ± 2°C • A maximum bank width of 1300 mm (The ducts of the stenter are 750 mm.…”
Section: Methodology To Design the Heat Exchangermentioning
confidence: 99%
“…The properties of the fluids and the fabric were determined using tables of thermodynamic properties [15]. The instantaneous power of the fans was measured using a Fluke 435 power quality analyzer.…”
Section: Energy Balancementioning
confidence: 99%