Liquid chromatography of metal complexes of N-disubstituted dithiocarbamic acids

Liquid Chromatography of Unstable Zinc Dithiocarbamates. Application to Rubber Gloves Analysis

“…This reaction is dependant on the metal (M) and on the solvent used. As far as ZnDTCs are concerned, this reaction was observed using apolar solvents and normal-phase LC [14]. In the present work, using acetonitrile as sample solvent and RPLC, no mixed ZnDTC were detected in standard mixtures.…”

“…L1-M-L1 + L2-M-L2 where L = ligand and M = metal), a ligand exchange reaction has been observed by different authors [2,5,14,15], resulting in the formation of mixed ligand dithiocarbamates (L1-M-L2) is obtained. This reaction is dependant on the metal (M) and on the solvent used.…”

“…Moreover, these compounds are also used as fungicides. Liquid chromatography (LC) is the method most commonly used for analysis of DTC [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15]. However, some metal-DTC complexes (e.g.…”