Lithium-ion capacitor using rice husk-derived cathode and anode active materials adapted to uncontrolled full-pre-lithiation

Kumagai, Seiji; Abe, Yusuke; Saito, Takato; Eguchi, Takuya; Tomioka, Masahiro; Kabir, Mahmudul; Tashima, Daisuke

doi:10.1016/j.jpowsour.2019.226924

Cited by 30 publications

(13 citation statements)

References 89 publications

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“…Among all the LIC devices, the 10-NaVO/C//AG (1.5:1) device shows the most outstanding electrochemical performance, delivering a high energy density of 118.9 Wh kg −1 at a power density of 220.6 W kg −1 and 43.7 Wh kg −1 even at 21,793.0 W kg −1 . The 10-NaVO/C//AG (1.5:1) device performs better than the YP50D//AG LIC device and several previously reported works as shown in in Figure 4 e [ 34 , 35 , 36 , 37 , 38 , 39 ]. Furthermore, a yellow LED was successfully lit by a full-charged 10-NaVO/C//AG (1.5:1) device, indicating the great potential in practical applications ( Figure 4 f).…”

Section: Resultsmentioning

confidence: 59%

Na0.76V6O15/Activated Carbon Hybrid Cathode for High-Performance Lithium-Ion Capacitors

Ren

Wang

et al. 2020

Materials

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Lithium-ion hybrid capacitors (LICs) are regarded as one of the most promising next generation energy storage devices. Commercial activated carbon materials with low cost and excellent cycling stability are widely used as cathode materials for LICs, however, their low energy density remains a significant challenge for the practical applications of LICs. Herein, Na0.76V6O15 nanobelts (NaVO) were prepared and combined with commercial activated carbon YP50D to form hybrid cathode materials. Credit to the synergism of its capacitive effect and diffusion-controlled faradaic effect, NaVO/C hybrid cathode displays both superior cyclability and enhanced capacity. LICs were assembled with the as-prepared NaVO/C hybrid cathode and artificial graphite anode which was pre-lithiated. Furthermore, 10-NaVO/C//AG LIC delivers a high energy density of 118.9 Wh kg−1 at a power density of 220.6 W kg−1 and retains 43.7 Wh kg−1 even at a high power density of 21,793.0 W kg−1. The LIC can also maintain long-term cycling stability with capacitance retention of approximately 70% after 5000 cycles at 1 A g−1. Accordingly, hybrid cathodes composed of commercial activated carbon and a small amount of high energy battery-type materials are expected to be a candidate for low-cost advanced LICs with both high energy density and power density.

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Section: Resultsmentioning

confidence: 59%

Na0.76V6O15/Activated Carbon Hybrid Cathode for High-Performance Lithium-Ion Capacitors

Ren

Wang

et al. 2020

Materials

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“…The performance of B-SWCNTs-TA150 was compared to conventional LIB cathodes − and the state-of-the-art Li-ion capacitor (LIC) cathodes (Tables S5 and S6). − For the LIB application, B-SWCNTs are superior to conventional LIB cathodes when operating at a high power. Conventional LIB materials are not capable of high current density because of their slow Li-ion storage mechanism and small surface area.…”

Section: Resultsmentioning

confidence: 99%

Highly Exfoliated and Functionalized Single-Walled Carbon Nanotubes as Fast-Charging, High-Capacity Cathodes for Rechargeable Lithium-Ion Batteries

Park

Lee

Cho

et al. 2019

ACS Appl. Mater. Interfaces

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Compared with traditional metal-oxide lithium-ion battery (LIB) cathodes, nanocarbon-based cathode materials have received much attention for potential application in LIBs because of their superior power density and long-term cyclability. However, their lithium-ion storage capacity needs further improvement for practical applications, and the trade-off between capacity and conductivity, when oxygen functional groups as lithium-ion storage sites are introduced to the nanocarbon materials, needs to be addressed. Here, we report a sequential oxidation–reduction process for the synthesis of single-walled carbon nanotubes (SWCNTs) for LIB cathodes with fast charging, long-term cyclability, and high gravimetric capacity. A LIB cathode based on highly exfoliated (d bundle < 10 nm) and oxygen-functionalized single-walled carbon nanotubes is obtained via the modified Brodie’s method using fuming nitric acid and a mild oxidant (B-SWCNTs). Post treatment including horn sonication and hydrogen thermal reduction developed surface defects and removed the unnecessary C–O groups, resulting in an increase in the Li-ion storage capacity. The B-SWCNTs exhibit a high reversible gravimetric capacity of 344 mA h g–1 at 0.1 A g–1 without noticeable capacity fading after 1000 cycles. Furthermore, it delivers a high gravimetric energy density of 797 W h kgelectrode –1 at a low gravimetric power density of 300 W kgelectrode –1 and retains its high gravimetric energy density of ∼100 W h kgelectrode –1 at a high gravimetric power of 105 W kgelectrode –1. These results suggest that the highly exfoliated, oxygen-functionalized single-walled carbon nanotubes can be applied to LIBs designed for high-rate operations and long cycling.

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“…Approximately 150 million tons of rice husk (RH) are generated annually and globally as agricultural waste 1 . RH is composed of approximately 80 mass% organic material (lignin, cellulose, hemicellulose, and others), and the rest are mainly silicon oxides (SiO x , 0 < x < 2) 2 . Rice, a silicicolous plant, adsorbs Si(OH) 4 from the soil for growth and accumulates SiO x in its husk 3 .…”

Section: Introductionmentioning

confidence: 99%

Role of SiOx in rice-husk-derived anodes for Li-ion batteries

Abe

Tomioka

Kabir

et al. 2022

Sci Rep

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The present study investigated the role of SiOx in a rice-husk-derived C/SiOx anode on the rate and cycling performance of a Li-ion battery. C/SiOx active materials with different SiOx contents (45, 24, and 5 mass%) were prepared from rice husk by heat treatment and immersion in NaOH solution. The C and SiOx specific capacities were 375 and 475 mAh g−1, respectively. A stable anodic operation was achieved by pre-lithiating the C/SiOx anode. Full-cells consisting of this anode and a Li(Ni0.5Co0.2Mn0.3)O2 cathode displayed high initial Coulombic efficiency (~ 85%) and high discharge specific capacity, indicating the maximum performance of the cathode (~ 150 mAh g−1). At increased current density, the higher the SiOx content, the higher the specific capacity retention, suggesting that the time response of the reversible reaction of SiOx with Li ions is faster than that of the C component. The full-cell with the highest SiOx content exhibited the largest decrease in cell specific capacity during the cycle test. The structural decay caused by the volume expansion of SiOx during Li-ion uptake and release degraded the cycling performance. Based on its high production yield and electrochemical benefits, degree of cycling performance degradation, and disadvantages of its removal, SiOx is preferably retained for Li-ion battery anode applications.

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Lithium-ion capacitor using rice husk-derived cathode and anode active materials adapted to uncontrolled full-pre-lithiation

Cited by 30 publications

References 89 publications

Na0.76V6O15/Activated Carbon Hybrid Cathode for High-Performance Lithium-Ion Capacitors

Na0.76V6O15/Activated Carbon Hybrid Cathode for High-Performance Lithium-Ion Capacitors

Highly Exfoliated and Functionalized Single-Walled Carbon Nanotubes as Fast-Charging, High-Capacity Cathodes for Rechargeable Lithium-Ion Batteries

Role of SiOx in rice-husk-derived anodes for Li-ion batteries

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