Remote sensing data proved to be a valuable resource in a variety of earth science applications. Using high-dimensional data with advanced methods such as machine learning algorithms (MLAs), a sub-domain of artificial intelligence, enhances lithological mapping by spectral classification. Support vector machines (SVM) are one of the most popular MLAs with the ability to define non-linear decision boundaries in high-dimensional feature space by solving a quadratic optimization problem. This paper describes a supervised classification method considering SVM for lithological mapping in the region of Souk Arbaa Sahel belonging to the Sidi Ifni inlier, located in southern Morocco (Western Anti-Atlas). The aims of this study were (1) to refine the existing lithological map of this region, and (2) to evaluate and study the performance of the SVM approach by using combined spectral features of Landsat 8 OLI with digital elevation model (DEM) geomorphometric attributes of ALOS/PALSAR data. We performed an SVM classification method to allow the joint use of geomorphometric features and multispectral data of Landsat 8 OLI. The results indicated an overall classification accuracy of 85%. From the results obtained, we can conclude that the classification approach produced an image containing lithological units which easily identified formations such as silt, alluvium, limestone, dolomite, conglomerate, sandstone, rhyolite, andesite, granodiorite, quartzite, lutite, and ignimbrite, coinciding with those already existing on the published geological map. This result confirms the ability of SVM as a supervised learning algorithm for lithological mapping purposes.