Distinct groupings of late Neoproterozoic tectonomagmatic and depositional events at 760 Ma, 685-670 Ma, 635-590 Ma and 590-545 Ma are recognized within the peri-Gondwanan margin of the Newfoundland Appalachians. This pre-Iapetan orogenic activity resulted in amalgamation of distinctive tectonic packages prior to deposition of a shale-rich platformal cover of terminal Neoproterozoic to Early Ordovician age, east of the Appalachian central mobile belt. The late Neoproterozoic successions chronicle, in part, the development of segments of a larger peri-Gondwanan orogenic system that was dispersed prior to, and variously reworked during, the protracted evolution of the southern Iapetus Ocean.The oldest orogenic events yet identified in the Newfoundland Avalonian belt occurred at and prior to 760 Ma and are manifest by the accumulation of submarine mafic volcanic rocks, the emplacement of oceanic gabbros, and the associated deposition of unique clastic and carbonate olistostromes. As early as 685 Ma, arc-related volcanic and associated arc-root plutonic complexes of felsic to intermediate composition developed along the orogenic belt in an overall contractional environment. These complexes, which are preserved together with amphibolite gneisses and associated intrusive rocks, were inhomogeneously deformed and then uplifted prior to the onset of widespread (635-590 Ma) volcanism, marine sedimentation, and coeval calc-alkaline plutonism, the products of which were deposited upon or emplaced into the 685-670 Ma basement. Locally, pre-600 Ma rocks have been inhomogeneously deformed prior to a complex volcanic, plutonic, and structural event (590-545 Ma), partly extensional and partly contractional in nature, during which the classical Ediacaranbearing and younger sedimentary successions of the Avalonian belt accumulated.Diverse tectonic elements that evolved prior to the Cambrian were variably dispersed at several times, perhaps most significantly during late Neoproterozoic orogenesis. Pronounced terminal Neoproterozoic and early Paleozoic tectonothermal events were recorded on the inboard Iapetan margin of the belt, while elsewhere, terminal Neoproterozoic through Cambro-Ordovician platformal sediments were deposited, in most cases without apparent hiatus. These contrasting peri-Gondwanan terranes were reamalgamated and again dispersed during complex transpressional orogenesis of Silurian age related to closure of the Iapetus Ocean, and ensuing collision of Gondwanan and Laurentian elements of the Appalachian orogen.