a b s t r a c tMid-infrared spectral observations Uranus acquired with the Infrared Spectrometer (IRS) on the Spitzer Space Telescope are used to determine the abundances of C 2 H 2 , C 2 H 6 , CH 3 C 2 H, C 4 H 2 , CO 2 , and tentatively CH 3 on Uranus at the time of the 2007 equinox. For vertically uniform eddy diffusion coefficients in the range 2200-2600 cm 2 s À1 , photochemical models that reproduce the observed methane emission also predict C 2 H 6 profiles that compare well with emission in the 11.6-12.5 lm wavelength region, where the t 9 band of C 2 H 6 is prominent. Our nominal model with a uniform eddy diffusion coefficient K zz = 2430 cm 2 s À1 and a CH 4 tropopause mole fraction of 1.6 Â 10 À5 provides a good fit to other hydrocarbon emission features, such as those of C 2 H 2 and C 4 H 2 , but the model profile for CH 3 C 2 H must be scaled by a factor of 0.43, suggesting that improvements are needed in the chemical reaction mechanism for C 3 H x species. The nominal model is consistent with a CH 3 D/CH 4 ratio of 3.0 ± 0.2 Â 10 À4 . From the best-fit scaling of these photochemical-model profiles, we derive column abundances above the 10-mbar level of 4.5 + 01.1/À0.8 Â 10 19 molecule-cm À2 for CH 4 , 6.2 ± 1.0 Â 10 16 molecule-cm À2 for C 2 H 2 (with a value 24% higher from a different longitudinal sampling), 3.1 ± 0.3 Â 10 16 molecule-cm À2 for C 2 H 6 , 8.6 ± 2.6 Â 10 13 molecule-cm À2 for CH 3 C 2 H, 1.8 ± 0.3 Â 10 13 molecule-cm À2 for C 4 H 2 , and 1.7 ± 0.4 Â 10 13 molecule-cm À2 for CO 2 on Uranus. A model with K zz increasing with altitude fits the observed spectrum and requires CH 4 and C 2 H 6 column abundances that are 54% and 45% higher than their respective values in the nominal model, but the other hydrocarbons and CO 2 are within 14% of their values in the nominal model. Systematic uncertainties arising from errors in the temperature profile are estimated very conservatively by assuming an unrealistic ''alternative'' temperature profile that is nonetheless consistent with the observations; for this profile the column abundance of CH 4 is over four times higher than in the nominal model, but the column abundances of the hydrocarbons and CO 2 differ from their value in the nominal model by less than 22%. The CH 3 D/CH 4 ratio is the same in both the nominal model with its uniform K zz as in the vertically variable K zz model, and it is 10% lower with the ''alternative'' temperature profile than the nominal model. There is no compelling evidence for temporal variations in global-average hydrocarbon abundances over the decade between Infrared Space Observatory and Spitzer observations, but we cannot preclude a possible large increase in the C 2 H 2 abundance since the Voyager era. Our results have implications with respect to the influx rate of exogenic oxygen species and the production rate of stratospheric hazes on Uranus, as well as the C 4 H 2 vapor pressure over C 4 H 2 ice at low temperatures.