Promoting the development of green technologies and replacing fossil fuel vehicles with electric ones can abate the environmental anxieties and issues associated with energy supply security. The increasing demand for electric vehicles requires an upgrade and expansion of the available charging infrastructure to accommodate the fast public adoption of this type of transportation. Ethiopia set a pro-electric cars policy and made them excise-free even before the first electric vehicle charging stations were launched by Marathon Motors Engineering in 2021. This paper presents the first ever technical, economic and environmental evaluation of electric vehicle charging stations powered by hybrid intermittent generation systems in three cities in Ethiopia. This paper tests this model using three different battery types: Lead-acid (LA), Flow-Zince-Bromine (ZnBr) and Lithium-ion (LI), used individually. Using these three battery technologies, the proposed hybrid systems are then compared in terms of system sizing, economy, technical performance and environmental stability. The results show that the feasible configuration of Solar Photovoltaic (PV)/Diesel Generator (DG)/ZnBr battery systems provide the lowest net present cost (NPC), with values of $2.97M, $2.72M and $2.85M, and cost of energy (COE), with values $0.196, $0.18 and $0.188, in Addis Ababa, Jijiga and Bahir Dar, respectively. Of all feasible systems, the Wind Turbine (WT)/PV/LI, PV/LI and WT/PV/LI configurations have the highest values of NPC and COE in Addis Ababa, Jijiga and Bahir Dar. Using this configuration, the results demonstrate that ZnBr battery is the most favorable choice because the economic parameters, including total NPC and COE, are found to be lowest.