The equations of statistical equilibrium for the population and depopulation of the electronic states of N2 have been solved for steady state normal auroral conditions. All vibrational levels for the seven lowest triplet electronic states (A, B, W, B', C, E, D) and the three lowest excited singlet electronic states (a, a', w) of N2 were included in the calculations. Recently measured auroral secondary electron spectra were employed to calculate the rates for electron impact excitation. The transition probabilities, electron impact excitation cross sections, and vibrationally dependent quenching rates used were a combination of the best available experimental and theoretical data. The results of these calculations are the absolute vibrational populations of all the electronic states. Intrasystem cascading and vibrationally dependent quenching were found to be important in determining the vibrational populations in the lower singlet and triplet excited electronic states. The predicted vibrational populations for the A and B triplet states agree well with the available experimental data. These calculations predict that a fairly large density of N• in excited roetastable states is produced under auroral conditions.
Detailed knowledge of the populations processes and emission properties of the valence excited states of Ns is required inorder to obtain a thorough understanding of auroral phenomenology. A significant fraction of the auroral energy incident at the top of the atmosphere appears either as emissions from Ns [Vallance Jones, 1971a, b, 1974] or in the form of metastable Ns electronic states which then participate in energy transfer processes with other atmospheric species. The population processes and emission characteristics for the Cailu state appear to be well understood, since there is now general agreement between auroral measurements of the second positive system and theoretical predictions of the band system intensities. However, no detailed analysis of the population processes for the valence singlet states of Ns under auroral conditions has been given that includes the specific contribu-ments of the population in the lowest levels of the B state under auroral conditions and conclude that their results agree better with the predictions of Cartwright et al. [1971, 1973] than with those of Shemansky et al. [1971]. These recent measurements appear to confirm the earlier predictions that intrasystem cascading is an important mechanism in determining the vibrational populations of certain singlet and triplet electronic states in Ns under auroral conditions. Recent laboratory measurements of the B state vibrational population under discharge conditions [Chen and Anderson, 1975] have also verified the predictions of substantial cascade contributions to the 13 lowest levels of the B state. The purpose of this paper is to present detailed vibrational populations for all the singlet and triplet excited states of Ns, within 12.5 eV of the ground state, excited under auroral tions from the various cascade process...