“…The study of the electronic structures of diamond-like carbon (DLC) thin films has attracted much attention for wide applications because of the films' interesting physical and chemical properties, such as high hardness, low friction coefficient, and chemical inertness. 1,2) As an example of applications, DLC films are used as coatings for the magnetic heads and media of hard disk drives. Physical properties of the DLC films have been related to the coordination of C atoms.…”
The coordination of C atoms in diamond-like carbon (DLC) thin films formed by Ar gas cluster ion beam (GCIB) assisted deposition using fullerene as a carbon source was investigated using X-ray photoelectron spectroscopy (XPS) and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. From the curve fitting analysis of XPS spectra of the C 1s core level, the absolute sp2 and sp3 contents in the DLC films formed by Ar GCIB-assisted deposition were evaluated for the first time. The absolute sp3 content of DLC films formed by the GCIB-assisted deposition at an acceleration voltage of 5 kV was the highest compared with that formed at 7 and 9 kV. In addition, the absolute sp2 contents evaluated from XPS spectra were compared to the relative sp2 contents evaluated from NEXAFS spectra.
“…The study of the electronic structures of diamond-like carbon (DLC) thin films has attracted much attention for wide applications because of the films' interesting physical and chemical properties, such as high hardness, low friction coefficient, and chemical inertness. 1,2) As an example of applications, DLC films are used as coatings for the magnetic heads and media of hard disk drives. Physical properties of the DLC films have been related to the coordination of C atoms.…”
The coordination of C atoms in diamond-like carbon (DLC) thin films formed by Ar gas cluster ion beam (GCIB) assisted deposition using fullerene as a carbon source was investigated using X-ray photoelectron spectroscopy (XPS) and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. From the curve fitting analysis of XPS spectra of the C 1s core level, the absolute sp2 and sp3 contents in the DLC films formed by Ar GCIB-assisted deposition were evaluated for the first time. The absolute sp3 content of DLC films formed by the GCIB-assisted deposition at an acceleration voltage of 5 kV was the highest compared with that formed at 7 and 9 kV. In addition, the absolute sp2 contents evaluated from XPS spectra were compared to the relative sp2 contents evaluated from NEXAFS spectra.
“…[1] As active materials, OPVs are also widely used in device studies for their tunable electronic properties and well-defined chemical structures. [2] The classic PPV oligomer, distyrylbenzene (DSB, 1) and its derivatives, [3] exhibit a nice blue fluorescence in dilute solution with a photoluminescence (PL) efficiency up to 90 %, but in the solid state the fluorescence is strongly quenched. This effect originates from intense crystallization characteristics and the pronounced p-p interaction encountered in the crystalline lattice of these planar conjugated molecules.…”
Ag/Ag + (0.1 M AgNO 3 ) electrode were used as the working, counter, and reference electrodes, respectively. Potentials were referenced to the ferrocene/ferrocenium ion (Fe/Fe + ) couple, and the scan rate was 100 mV s.
“…[1] Most of the synthetic processes require relatively drastic conditions, and the carbon source may be obtained by ionization, [2] ion sputtering, [3] or laser ablation. [4] In a graphitic structure, the 3.4 Å distance between each layer allows significant p-p interactions.…”
mentioning
confidence: 99%
“…[1] As active materials, OPVs are also widely used in device studies for their tunable electronic properties and well-defined chemical structures. [2] The classic PPV oligomer, distyrylbenzene (DSB, 1) and its derivatives, [3] exhibit a nice blue fluorescence in dilute solution with a photoluminescence (PL) efficiency up to 90 %, but in the solid state the fluorescence is strongly quenched. This effect originates from intense crystallization characteristics and the pronounced p-p interaction encountered in the crystalline lattice of these planar conjugated molecules.…”
mentioning
confidence: 99%
“…Tetrahedral amorphous carbon films have been a subject of investigation during the past decade due to their unique properties, which are found to be between those of diamond and graphite. [1] Most of the synthetic processes require relatively drastic conditions, and the carbon source may be obtained by ionization, [2] ion sputtering, [3] or laser ablation. [4] In a graphitic structure, the 3.4 Å distance between each layer allows significant p-p interactions.…”
Aziridination of graphitic carbon nanocapsules (CNCs) followed by pyrolysis at 700 °C at ambient pressure yields tetrahedral amorphous carbon nanoballs (CNBs, see Figure). Because of the pyramidal character of some of the double bonds in the derivatized CNCs, a radical chain mechanism is proposed to rationalize the transformation of C sp2 hybridization in the CNCs to C sp3 hybridization in the CNBs.
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