The hybridization
of graphene with other inorganic nanostructures
has endowed graphene with enhanced and varied functionalities. Here
we demonstrate a facile and improved approach to convert biodegradable
cedar wood into graphene embedded with various metal nanocrystals
(cedar-LIG-M, LIG is laser-induced graphene, M = Cu, Co, Ni, Fe, NiFe)
by sonication-assisted soaking and one-step CO2 laser scribing.
Organic biomass was transformed to hierarchical porous graphene via
laser induction, whereas metal salts were reduced to elemental metals
simultaneously by the carbothermal reaction and reducing atmosphere
generated during the lignocellulose decomposition. The as-prepared
cedar-LIG-M possesses an ordered porous structure, good conductivity,
unique ferromagnetic behavior and excellent electrochemical catalytic
performance. As a demonstration, the cedar-LIG-NiFe electrode has
a low overpotential of 296 mV at a current density of 10 mA cm–2 for oxygen evolution reactions. The performance of
the electrode continued to improve at the initial testing stage due
to the in situ activation as a result of the increased oxidation states
of nickel and iron during electrochemical oxygen evolution. In addition,
the cedar-LIG-NiFe could also serve as an electromagnetic interference
shielding material with shielding effectiveness up to 54 dB. The simplicity
and versatility of this technique provides a route for the synthesis
of various carbon-based hybrid materials with potential applications
of the products in many different fields, such as energy storage,
electrocatalysis, electromagnetic interference shielding, and water
treatment.