2007
DOI: 10.1002/cvde.200606554
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Low‐Pressure PECVD of Nanoparticles in Carbon Thin Films from Ar/H2/C2H2 Plasmas: Synthesis of Films and Analysis of the Electron Energy Distribution Function

Abstract: A study of the synthesis of carbon nanoparticles embedded in carbon thin films deposited by radiofrequency (RF) (13.56 MHz) Ar/H 2 (4 %)/C 2 H 2 plasmas is presented. The carbon nanospheres exhibit an amorphous structure that is clearly observed at 300 W, under 0.1 Torr, and grows in size with increasing C 2 H 2 between 1 % and 20 %. Above a C 2 H 2 concentration threshold (20 % in this case) carbon nanoparticles are no longer formed. In order to study possible changes in the plasma kinetics, optical emission … Show more

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Cited by 7 publications
(3 citation statements)
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“…The minimum reflection occurs with a 35%v/v loading of TEOS binder which produces a hardness of 4.4 GPa. This value is comparable to various other nanoparticle protective coatings. A more common and simple approach used for mechanical testing is a pencil hardness test. A hardness value of 4.4 GPa will pass a 5H pencil test, which is above the industry standard of 3H required for practical applications .…”
Section: Resultssupporting
confidence: 52%
“…The minimum reflection occurs with a 35%v/v loading of TEOS binder which produces a hardness of 4.4 GPa. This value is comparable to various other nanoparticle protective coatings. A more common and simple approach used for mechanical testing is a pencil hardness test. A hardness value of 4.4 GPa will pass a 5H pencil test, which is above the industry standard of 3H required for practical applications .…”
Section: Resultssupporting
confidence: 52%
“…Here, the inert gas Ar is the carrier gas and is used as a dilutant when r CH or r H is varied. Such gas mixtures are commonly used in carbon nanostructure synthesis experiments [42][43][44]. The ion and electron temperature are assumed constant throughout the sheath.…”
Section: Numerical Model and Basic Equationsmentioning
confidence: 99%
“…Various particles move towards the substrate and are deposited on it to form amorphous thin films. The resulting thin film is then incorporated into industrial devices; in particular, electronic devices, solar cells and thin film transistors for controlling liquid crystal display (LCD) panels [3,4].…”
Section: Introductionmentioning
confidence: 99%