2021
DOI: 10.1016/j.apcatb.2021.120442
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Low Ru loading RuO2/(Co,Mn)3O4 nanocomposite with modulated electronic structure for efficient oxygen evolution reaction in acid

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Cited by 169 publications
(101 citation statements)
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“…By comparing published literature, weaker adsorption of Ru and O would lead to lower free energy for the RDS and exhibit excellent OER activity, which matches up with our calculations. [5,42] In addition, after incorporation with Cr, more unoccupied states are produced in the e g state of Ru. [43] This is further supported by the DFT calculated partial density of states results for Ru sites on the surface (Figure S21b, Supporting Information).…”
Section: Resultsmentioning
confidence: 99%
“…By comparing published literature, weaker adsorption of Ru and O would lead to lower free energy for the RDS and exhibit excellent OER activity, which matches up with our calculations. [5,42] In addition, after incorporation with Cr, more unoccupied states are produced in the e g state of Ru. [43] This is further supported by the DFT calculated partial density of states results for Ru sites on the surface (Figure S21b, Supporting Information).…”
Section: Resultsmentioning
confidence: 99%
“…), revealing the superior utilization of Ru than other Ru-based electrocatalysts in acidic media (Figure 4c and Table S4, Supporting Information). [53,[58][59][60][61][62][63][64][65] To the best of 4f). The RuO 2 -WC NPs exhibit a C dl value of 17.9 mF cm À 2 , which is 2.3-fold higher than that of Ru-WC NPs (7.9 mF cm À 2 ) and 4.97-fold higher than that of WC NPs (3.6 mF cm À 2 ), suggesting a more electrochemical active surface area to expose abundant of active sites.…”
Section: Methodsmentioning
confidence: 99%
“…S11†). What is even more remarkable is that among the most recent ruthenium-based acidic OER electrocatalysts reported in 2021 (Table 1), 44–49 In 0.17 Ru 0.83 O 2 -350 has the highest mass activity (1094.90 A g Ru −1 @ η = 300 mV) and the lowest Tafel slope of 32.62 mV dec −1 (Fig. 3b, S12 and Table S5†).…”
Section: Resultsmentioning
confidence: 93%