Low-temperature electrochemical codeposition of aluminum-neodymium alloy in a highly stable solvate ionic liquid

LiNO3-Supported Electrodeposition of Metallic Nd from Nd-Containing Solvate Ionic Liquid

“…These are ascribed to the Laporte-forbidden intraconfigurational electronic transitions within the 4f 3 shell of Nd­(III). The high-intensity, well-defined absorption bands at 524.6, 583.4, and 740.8 nm could be assigned to the hypersensitive 4 I 9/2 → 4 G 9/2 , 4 I 9/2 → 2 G 7/2 , and 4 I 9/2 → 4 F 7/2 transitions, respectively, which result in an extremely fine structure. , The other common absorption peaks near the UV region were related to the internal structures of DMI and [(CF 3 SO 3 ) 3 ] − .…”

“…Several studies have successfully achieved the electrodeposition of various metals from the corresponding metal-containing ILs. − For instance, Al-containing solvate ILs are inexpensive and readily available and have many of the other benefits common to ILs. ,, Hence, they are highly desirable for the electrodeposition of active metals and alloys, including Al, Li, Al–Li, and Al–Nd alloys. , These can be synthesized by mixing the Lewis acid AlCl 3 with the matching neutral ligands. Hence, the strategy of exploiting neutral ligand complexation of metal cations to form new NLILs for metal electrodeposition is considered effective.…”

“…25−28 For instance, Al-containing solvate ILs are inexpensive and readily available and have many of the other benefits common to ILs. 25,29,30 Hence, they are highly desirable for the electrodeposition of active metals and alloys, including Al, Li, Al−Li, and Al−Nd alloys. 29,30 These can be synthesized by mixing the Lewis acid AlCl 3 with the matching neutral ligands.…”

“…25,29,30 Hence, they are highly desirable for the electrodeposition of active metals and alloys, including Al, Li, Al−Li, and Al−Nd alloys. 29,30 These can be synthesized by mixing the Lewis acid AlCl 3 with the matching neutral ligands. Hence, the strategy of exploiting neutral ligand complexation of metal cations to form new NLILs for metal electrodeposition is considered effective.…”

Fabrication of Monolithic Catalysts: Comparison of the Traditional and the Novel Green Methods

“…Electrodeposition is an electrochemical process occurring at the interface between electrode and electrolyte, which has been applied in the field of surface structure modification for a long time [53].…”