Hydrothermal synthesis of barium titanate was done by both
microwave heating and
conventional heating. The synthesis process was evaluated by
examining samples at different
processing times by X-ray diffraction. For samples produced by
both heating methods, the
metastable cubic phase crystallized first and gradually transformed to
a tetragonal phase.
Microwave synthesis showed advantages of shortened crystallization
time, increased c/a ratio,
and upon sintering led to a larger degree of increased
c/a ratio. Elemental analysis
showed
a smaller Ti/Ba ratio and larger relative amount of Cl-
ion in the microwave-treated sample
than those in a conventionally treated sample. Sintering at 850
°C for both samples resulted
in the samples exhibiting a clear transition temperature of around 125
°C as measured by
DSC.