Scatterometry, defined as the angle resolved characterization of light scattered from a surface, is an attractive tool for the metrology of semiconductor devices. It is simple, rapid, non destructive, relatively inexpensive and can be used in-situ. This paper illustrates the use of scatterometry to characterize fine pitch gratings having linewidths 0. lj.m. These gratings diffract light only in the zeroth order as their pitch-to-wavelength ratio is much smaller than one, hence they are also known as 0-order gratings.Metrology of 0-order gratings brings forth new issues, chiefly (i) lack of diffraction sensitivity to variation in the grating parameters, and (ii) non-uniqueness of the "diffraction signatures" . We use the gratings in conical mounting to enhance the diffraction sensitivity and have circumvented the non-uniqueness issue in two ways: (i) limiting the parameter space of the search algorithm and (ii) using different incident field polarizations. We employ constrained optimization techniques to efficiently scan the parameter space.Our results agree well with cross-sectional SEM measurements and demonstrate the feasibility of scatterometry for these structures. We are also using shorter wavelengths for the metrology of 0-order gratings, and preliminary results using ?=442 nm demonstrate that the diffraction is more sensitive to the variation in grating linewidth and etch depth.Critical dimensions (CD's) of the current semiconductor devices are getting smaller, hence making the metrology of these structures more difficult and yet more important. Although SEM's are the defacto standard for the metrology of these devices, they suffer from a number of drawbacks, mainly among these is their precision, related to the lack of robust algorithm to extract the relevant dimensional information and their inability to be used in on-line processing. An attractive alternate optical metrology tool is scatterometry, which can be defined as the angle-resolved characterization of light scattered from a surface; for metrology purposes the surfaces to be characterized are gratings or device patterns that have periodic structure.Metrology of gratings using scatterometry is discussed in detail in references1' 2, and is briefly described here. Basically experimental data is taken on the grating to be characterized using a scatterometer, and a theoretical model is constructed to relate this experimental data to the unknown parameters of the grating being measured.Data from a scatterometer is the variation in diffraction efficiency as a function of angle of incidence in any given diffracted "order". This type of data is interchangeably called the "diffraction curve", "2-8 plot" or the scatter "signature". Figure 1 shows a typical scatter "signature" from a 0.8 J.tm pitch grating structure. For 0-order gratings, only the 0th order is available for measurement; all other orders are evanescent.The theoretical model consists of determining the diffraction efficiencies of the given grating using rigorous grating theory. These diffracti...