We have synthesized Yb 2+ -activated Si 6−z Al z O z N 8−z (0.05 z 2.3, 0.03 mol% Yb 2+ 0.7 mol%) green phosphors by solid-state reaction at 1900• C for 2 h under a nitrogen pressure of 1.0 MPa. Phase purity, photoluminescence and its thermal quenching were investigated. A single phase was obtained for all values of z and Yb 2+ concentration. A distinct emission band was observed at 540 nm originating from the 5d-4f electronic transition in Yb 2+ under 480 nm excitation. The photoluminescence properties mainly depended on the Yb 2+ concentration and chemical composition of the matrix. The resultant phosphor showed high thermal stability, that is, the emission intensity at 150• C was about 82% of that measured at room temperature. The experimental results indicate that β-SiAlON : Yb 2+ is a potential green phosphor for white light-emitting diodes (LEDs), which use blue LEDs as the primary light source.