“…Therefore, it is regarded as a suitable polymer for insulations and binding materials due to several of its distinct features, including amazing thermal and chemical stability, excellent relative permittivity, light weight, flexibility, and low density 3 . PVDF, which has the molecular formula (CH 2 CF 2 ) n , can be cast in a variety of polymorphs, including polar β, γ, δ, and nonpolar α‐phases 4,5 . The degree of intensity of the β‐phase predominantly controls the pyro‐, piezo‐, and ferroelectric activity in PVDF, so from the various phases α and β‐phase are interesting to study 6…”