Samples of YBa2Cu3O7−δ,
having about 30% Y2BaCuO5, were prepared with a melt-process method by adding
B2O3
up to 0.5 wt% to the oxides. The structural and superconducting properties
of the samples were studied by x-ray diffraction, x-ray fluorescence,
scanning electron microscope, magnetization and magneto-optic techniques.
B2O3 additions
during the melt-processing enlarge intergrain regions that weaken the conduction links between the grains.
Tc drops by 1.0–6.0 K,
and at 50 K Jc
decreases from about 1.6 × 104
to 1.8 × 103 A cm−2
with B2O3
additions up to 0.5 wt%. A secondary peak was observed in the
Jc
versus field plot of the boron-free sample that decreases with boron additions. At 50 K the intragrain
Jc
values of the boron-free sample were about 12% higher than the intergrain
Jc value, and such
differences increase with B2O3
additions. These observations, together with the enlargements of the intergrain regions with
B2O3
additions, suggest that most of the boron atoms take part and reside at grain boundaries.