Effects of nitrogen contents and substrate temperatures to the microstructure and magnetic properties of the FeCoN films have been investigated. According to the TEM and x-ray Scherrer's equation analyses, we found that the grain size of films with substrate temperature below 200°C is roughly about 13 nm, however, it increases very fast for films with substrate temperature above 300°C. N content in the films is saturated to 30 at. %, as N 2 flow ratio N 2 /͑ArϩN 2 ) is higher than 5 vol. %. From the magnetization studies, we have found that the saturation magnetization 4M s of the optimum samples ͑with the substrate temperature near 200°C͒ is 23.9 kG. The improvement of the magnetic properties is attributed to the combination of ␣-Fe with N to form the high magnetic moment FeN phases.