Exploring the relationship between intriguing physical
properties
and structural complexity is a central topic in studying modern functional
materials. Co3Sn2S2, a newly discovered
kagome-lattice magnetic Weyl semimetal, has triggered intense interest
owing to the intimate coupling between topological semimetallic states
and peculiar magnetic properties. However, the origins of the magnetic
phase separation and spin glass state below T
C in this ordered compound are two unresolved yet important
puzzles in understanding its magnetism. Here, we report the discovery
of local symmetry breaking surprisingly co-emerges with the onset
of ferromagnetic order in Co3Sn2S2, by a combined use of neutron total scattering and half-polarized
neutron diffraction. An anisotropic distortion of the cobalt kagome
lattice at the atomic/nano level is also found, with distinct distortion
directions among the two Co1 and four Co2 atoms. The mismatch of local
and average symmetries occurs below T
C, indicating that Co3Sn2S2 evolves
to an intrinsically lattice disordered system when the ferromagnetic
order is established. The local symmetry breaking with intrinsic lattice
disorder provides new understanding of the puzzling magnetic properties.
Our density functional theory (DFT) calculation indicates that the
local symmetry breaking is expected to reorient local ferromagnetic
moments, unveiling the existence of the ferromagnetic instability
associated with the lattice instability. Furthermore, DFT calculation
unveils that the local symmetry breaking could affect the Weyl property
by breaking the mirror plane. Our findings highlight the fundamentally
important role that the local symmetry breaking plays in advancing
our understanding on the magnetic and topological properties in Co3Sn2S2, which may draw attention to explore
the overlooked local symmetry breaking in Co3Sn2S2, its derivatives and more broadly in other topological
Dirac/Weyl semimetals and kagome-lattice magnets.