2003
DOI: 10.1063/1.1561166
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Magnetic study of an amorphous conducting polyaniline

Abstract: We show that newly found BF3-doped polyaniline, though highly conducting, remains amorphous. Magnetic studies reveal many unusual properties, while suggesting that the intrinsic conductivity of this system is significantly larger than all other known forms of conducting polyaniline, establishing it as an interesting class of highly conducting amorphous polymer.

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Cited by 18 publications
(10 citation statements)
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“…1(a) demonstrates several sharp peaks approximately at 9.80, 17.03, 18.45, 20.51, 23.06, 24.19, and 25.04 corresponding to crystal plane (001), (012), (003), (100), (020), (110), and (111), respectively. We do admit that the XRD pattern for the DBSA-doped-PAni is not similar to the reported one of PAni, [9][10][11][12] probably due to the difference of preparing method and the effect of DBSA in media. Furthermore, it is known from the literature 9-12 that the XRD of PAni clearly suggests that the system is generally amorphous.…”
contrasting
confidence: 59%
“…1(a) demonstrates several sharp peaks approximately at 9.80, 17.03, 18.45, 20.51, 23.06, 24.19, and 25.04 corresponding to crystal plane (001), (012), (003), (100), (020), (110), and (111), respectively. We do admit that the XRD pattern for the DBSA-doped-PAni is not similar to the reported one of PAni, [9][10][11][12] probably due to the difference of preparing method and the effect of DBSA in media. Furthermore, it is known from the literature 9-12 that the XRD of PAni clearly suggests that the system is generally amorphous.…”
contrasting
confidence: 59%
“…In addition, the broad diffraction peak in the 2q range of 20-30 can be assigned to amorphous PANI. 35 To further verify the presence of PANI in PBAs@PANI, fourier transform infrared (FT-IR) and Raman spectra of PBAs, PANI and PBAs@PANI nanocubes were also collected. As shown in Fig.…”
Section: Resultsmentioning
confidence: 99%
“…e nanoparticles of AgCl are not identified by this analysis because they are immediately transformed into metal Ag by the light photons. ese Terminal halogen atoms stretching vibrations (υ Ag-Cl ) [8] interpretations prove that nanocomposites are formed by polyaniline, silver metal, and AgCl nanoparticles.…”
Section: Uv-vis Spectroscopymentioning
confidence: 99%
“…e amorphous character of polyaniline is given by a wide curvature located around 2theta ≈24.9° [7,8].…”
Section: Drx Diffractogrammentioning
confidence: 99%