2018
DOI: 10.1021/acs.jpcc.8b06471
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Magnetophoretic Sprinting: A Study on the Magnetic Properties of Aqueous Lanthanide Solutions

Abstract: Droplets of aqueous solutions of trivalent lanthanide ions (Ln 3+) were formed inside an immiscible fluid. The motion of the droplets, induced by the magnetic field of a Nd−Fe−B permanent magnet, was measured. By using the relationship between the magnetophoretic velocity, the magnetic force, and the frictional coefficient, a good estimate of the magnetic susceptibility was obtained. The impact of the magnetic susceptibility of each Ln 3+ ion on the magnetophoresis was analyzed. Additionally, the influence of … Show more

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Cited by 15 publications
(11 citation statements)
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“…59 The resulting motion of the magnetic material in a viscous medium is called magnetophoresis. 60 The intensity of the magnetophoretic force scales linearly with the volume of the object; 59,60 hence the SBS protocol was crucial for the selection of Ag-Fe NPs with large mass and maximum response to the magnetic eld. Also, the local eld enhancement is size-dependent, 48,61 with optimum conditions in the size range comparable to that achieved for Ag-Fe NPs by the application of the SBS protocol, that is between tens and few hundreds of nm.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…59 The resulting motion of the magnetic material in a viscous medium is called magnetophoresis. 60 The intensity of the magnetophoretic force scales linearly with the volume of the object; 59,60 hence the SBS protocol was crucial for the selection of Ag-Fe NPs with large mass and maximum response to the magnetic eld. Also, the local eld enhancement is size-dependent, 48,61 with optimum conditions in the size range comparable to that achieved for Ag-Fe NPs by the application of the SBS protocol, that is between tens and few hundreds of nm.…”
Section: Resultsmentioning
confidence: 99%
“…However, magnetic amplication changed with PEG concentration and length, which can be explained by the reverse osmotic effect only if the polymer coating also inuences the overall concentration of Ag-Fe NPs attracted at the site of analysis. For instance, although PEG chains are indispensable for Ag-Fe NP stability and reversibility of the magnetic amplication process, it should be noted that polymer coating also inuences the hydrodynamic friction coefficient of the nanostructure, 59,60,67 which measures the resistance to particle migration under the action of the magnetic force. However, the efficiency of magnetic migration, expressed as the ratio of solution absorbance at the surface plasmon resonance maximum (at 410 nm) before (Abs (H ¼ 0)) and aer (Abs (H s 0)) magnetic focusing of Ag-Fe NPs, was not correlated to the PEG length in our experiments.…”
Section: Resultsmentioning
confidence: 99%
“…When a solution is magnetized in an external field, it acquires a magnetic energy E mag [J m −3 ] which is expressed as: 3,7,8,[24][25][26]…”
Section: Theoretical Backgroundmentioning
confidence: 99%
“…Considering these values, a magnetic separation of ions could be deemed an Icarian endeavor. Nevertheless, attempts of rare earth ion separation in a magnetically modified Clusius-Dickel thermal diffusion column , were reported by Ida and Walter Noddack in the 1950s. After a 50 year hiatus, interest in the effects of magnetic field gradients on ionic solutions has been revived. ,, Magneto-convection only arises when the magnetic field gradient force is rotational, which necessitates a susceptibility gradient and magnetic field gradient that are non-parallel . Interferometric measurements generated evidence of magnetic ion enrichment around the surface of an evaporating solution containing a single paramagnetic species. The inhomogeneity in these systems is caused by the input of thermal energy, which is the driving force for the concentration change and essentially a distillation process.…”
Section: Introductionmentioning
confidence: 99%