Long-term measurements of ambient particulate matter less than 2.5 μm in diameter (PM 2.5 ) and its chemical compositions were performed at a rural site in Korea from December 2005 to August 2009. The average PM 2.5 concentration was 31 μg m −3 for the whole sampling period, and showed a slightly downward annual trend. The major components of PM 2.5 were organic carbon, SO 4 2− , NO 3 − , and NH 4 + , which accounted for 55 % of total PM 2.5 mass on average. For the top 10 % of PM 2.5 samples, anionic constituents and trace elements clearly increased while carbonaceous constituents and NH 4 + remained relatively constant. Both Asian dust and fog events clearly increased PM 2.5 concentrations, but affected its chemical composition differently. While trace elements significantly increased during Asian dust events, NO 3 − , NH 4 + and Cl were dramatically enhanced during fog events due to the formation of saturated or supersaturated salt solution. The backtrajectory based model, PSCF (Potential Source Contribution Function) identified the major industrial areas in Eastern China as the possible source areas for the high PM 2.5 concentrations at the sampling site. Using factor analysis, soil, combustion processes, non-metal manufacture, and secondary PM 2.5 sources accounted for 77 % of the total explained variance.