Dexteropreneurship is a new concept that supplies a new view of the ambidexterity of entrepreneurship and thinking that can reveal the configuration of proactive, innovative, and risk-taking in the ambidexterity of an entrepreneur's activities. Based on the topic' novelty, there has been no term' conceptualization and a merged view of dexteropreneurship. The purpose of this paper is to discuss dexteropreneurship through a Systematic Literature Review (SLR), which develop a conceptualization that purpose to have a better understanding of how entrepreneurs balance exploratory and exploitative processes and how to configure entrepreneurship to support exploitation and exploitation. Derived from this, this paper aims to provide literature based on conceptualization providing a practical implementation for practitioners along with a research agenda that is a valuable contribution to new paradigms and possible future research of dexteropreneurship.