Manganese Complexes Containing Nonmetallic Elements

Treichel, P. M.

doi:10.1016/b978-008046519-7.00048-4

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2023

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“…While the chemistry of phosphido ligands on other elements has been reviewed, [32,33] it has not been for manganese. Phosphinidine (RP 2− ) bridged binuclear complexes has been reviewed [28a,34] . Therefore, the following review is an undertaking to survey the synthesis of the class of manganese compounds (Scheme 1) that generally can be described as dinuclear Mn(I) phosphido and hydride complexes, and aspects of their reactivity that make them relevant to hydrogenative catalysis.…”

Section: Introductionmentioning

confidence: 99%

Dinuclear Mn(I) Complexes with Phosphido and Hydrido Bridges: Synthesis, Reactivity, and Hydrogenative Catalysis

Lacy

Abhyankar

2023

Chemistry A European J

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A class of organomanganese hydrogenation catalysts was recently rediscovered. These are simple dinuclear Mn(I) carbonyl compounds with phosphido (PR 2 À ) and hydrido (H À ) bridges. This class of compounds has been known since the 1960's, and they have rich coordination chemistry and reactivity. Given their recently discovered potential for catalytic applications, a fresh look at this class of compounds was necessary. Hence, this Review comprehensively covers the synthesis, reactivity, and catalysis of this interesting class of molecules.

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Section: Introductionmentioning

confidence: 99%