Iron impurities present in the crystal structure of kaolin
minerals
or in accessory species are frequently encountered in clay deposits.
As knowledge of the location and states of the iron is crucial when
modifying the properties of clays by activation, it is important that
new deposits are well characterized in terms of the amount and location
of this metal. The Western Australia Noombenberry deposit has been
identified as a large resource of kaolin composed largely of halloysite
and kaolinite. We sampled six from one hundred drill holes and grouped
them according to major mineral and iron impurities. First, we characterized
them to understand the source of iron impurities. Then, we performed
three physicochemical activation processes of samples involving acid
treatment (by 3 M HCl), heating at 600 °C, and a combination
of both. State-of-the-art tools, including X-ray diffraction, X-ray
photoelectron spectroscopy, scanning and transmission electron microscopy,
and nuclear magnetic resonance, revealed the properties of kaolin,
iron impurities, and the changes incurred after activation. The iron
impurities were found to be linked to non-kaolin minerals, i.e., in
mica or illite. Once the iron was removed mainly by acid activation,
the surface area, pore volume, and negative surface charges increased,
and that was significant for halloysite-rich samples. These properties
helped adsorb N2 gas compared to the raw kaolin. Therefore,
knowing the iron’s location and states in associated mineral
species and their dissolution/retention may expand the scope of material
development for gas adsorption. They are also useful in other applications
like clay purification and adsorbent or additive formulations.