In the framework of the maximum entropy production rate principle, a simple model for Teflon material ablation by arc radiation is introduced. The model predicts a vapour temperature T and an effective ablation enthalpy Δheff of about 3200 K and 11 MJ kg−1, respectively. These values are constant for radiation fluxes Qrad ≪ pΔheff/c (≈1010 W m−2 at pressure p ≈ 10 bar and sound velocity c≈ 103 m s−1). For larger Qrad the model is not self-consistent and must be generalized. In the range of self-consistency, the results are in accordance with observations reported in the relevant literature on nozzle ablation in gas circuit breakers or model tubes.