Mathematical Representation of Thermodynamic Properties. Carbazole Solubilities in Binary Alkane + Dibutyl Ether and Alkane + Tetrahydropyran Solvent Mixtures

Acree, William E.; McCargar, James W.; Zvaigzne, Anita I.; Teng, I.-Lih

doi:10.1080/00319109108030630

Cited by 154 publications

(118 citation statements)

References 19 publications

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“…Experimental solubility data are considered to be internally consistent if the measured x i values can be accurately described by either Eq. (8) and/or Eq. (9).…”

Section: àLn Xmentioning

confidence: 99%

IUPAC-NIST Solubility Data Series. 98. Solubility of Polycyclic Aromatic Hydrocarbons in Pure and Organic Solvent Mixtures: Revised and Updated. Part 1. Binary Solvent Mixtures

Acree

2013

Journal of Physical and Chemical Reference Data

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This work updates Vols. 54, 58, and 59 in the IUPAC Solubility Data Series and presents solubility data for polycyclic aromatic hydrocarbon solutes dissolved in binary organic solvent mixtures. Published solubility data for anthracene, naphthalene, phenanthrene, phenothiazine, and pyrene that appeared in the primary literature between 1995 to the end of 2011 are compiled and critically evaluated. Experimental solubility data for 360 different solute-binary solvent systems are included in the volume. Solubility data published prior to 1995 were contained in three earlier volumes (Vols. 54, 58, and 59) and are not repeated in this volume.

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“…Experimental solubility data are considered to be internally consistent if the measured x i values can be accurately described by either Eq. (8) and/or Eq. (9).…”

Section: àLn Xmentioning

confidence: 99%

IUPAC-NIST Solubility Data Series. 98. Solubility of Polycyclic Aromatic Hydrocarbons in Pure and Organic Solvent Mixtures: Revised and Updated. Part 1. Binary Solvent Mixtures

Acree

2013

Journal of Physical and Chemical Reference Data

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“…Acree and co-workers [4][5][6] suggested the combined NIBS/ Redlich-Kister model * To whom correspondence should be addressed. E-mail: acree@unt.edu.…”

Section: Resultsmentioning

confidence: 99%

Solubility in Binary Solvent Mixtures: Anthracene Dissolved in Alcohol + Acetonitrile Mixtures at 298.2 K

et al. 2003

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Experimental solubilities are reported for anthracene dissolved in six binary alcohol + acetonitrile solvent mixtures at 25°C. The alcohol cosolvents studied were methanol, ethanol, 1-pentanol, 2-pentanol, 2-methyl-1-pentanol, and 4-methyl-2-pentanol. Results of these measurements are used to test a mathematical representation based upon the combined nearly ideal binary solvent (NIBS)/Redlich-Kister equation. For the six systems studied, the combined NIBS/Redlich-Kister equation was found to mathematically describe the experimental data to within an overall average absolute deviation of approximately (0.7%.

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“…Acree and co-workers [4][5][6] suggested the Combined NIBS/ Redlich-Kister model, as a possible mathematical representation for describing how experimental isothermal solubility of a crystalline solute dissolved in a binary solvent mixture varies with binary solvent composition. In eq 1, x B 0 and x C 0 refer to the initial mole fraction composition of the binary solvent calculated as if solute (A) were not present, N is the number of curve-fit parameters used, and (x A sat ) i is the saturated mole fraction solubility of the solute in pure solvent i.…”

Section: Resultsmentioning

confidence: 99%

Solubility in Binary Solvent Mixtures: Pyrene Dissolved in Alcohol + Acetonitrile Mixtures at 299.2 K

et al. 2003

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Experimental solubilities are reported for pyrene dissolved in seven binary alcohol + acetonitrile solvent mixtures at 26 °C. The alcohol cosolvents studied were 1-propanol, 2-propanol, 1-butanol, 2-butanol, 2-methyl-1-propanol, 3-methyl-1-butanol, and 2-pentanol. Results of these measurements are used to test a mathematical representation based upon the Combined Nearly Ideal Binary Solvent (NIBS)/ Redlich-Kister equation. For the seven systems studied, the Combined NIBS/Redlich-Kister equation was found to mathematically describe the experimental data to within an overall average absolute deviation of approximately (1.0%.

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Mathematical Representation of Thermodynamic Properties. Carbazole Solubilities in Binary Alkane + Dibutyl Ether and Alkane + Tetrahydropyran Solvent Mixtures

Cited by 154 publications

References 19 publications

IUPAC-NIST Solubility Data Series. 98. Solubility of Polycyclic Aromatic Hydrocarbons in Pure and Organic Solvent Mixtures: Revised and Updated. Part 1. Binary Solvent Mixtures

IUPAC-NIST Solubility Data Series. 98. Solubility of Polycyclic Aromatic Hydrocarbons in Pure and Organic Solvent Mixtures: Revised and Updated. Part 1. Binary Solvent Mixtures

Solubility in Binary Solvent Mixtures: Anthracene Dissolved in Alcohol + Acetonitrile Mixtures at 298.2 K

Solubility in Binary Solvent Mixtures: Pyrene Dissolved in Alcohol + Acetonitrile Mixtures at 299.2 K

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