In this work we have realized plasma diagnosis produced by Laser (LPP), by means of emission spectroscopy in a Laser Shock Processing (LSP). The LSP has been proposed as an alternative technology, competitive with classical surface treatments. The ionic species present in the plasma together with electron density and its temperature provide significant indicators of the degree of surface effect of the treated material. In order to analyze these indicators, we have realized spectroscopic studies of optical emission in the laser-generated plasmas in different situations. We have worked focusing on an aluminum sample (A12024) in air and/or in LSP conditions (water flow) a Q-switched laser of Nd:YAG (A. = 1.06 (im, 10ns of pulse duration, running at 10Hz repetition rate). The pulse energy was set at 2,5 J per pulse. The electron density has been measured using, in every case, the Stark broadening of H Balmer a line (656.27 nm). In the case of the air, this measure has been contrasted with the value obtained with the line of 281.62 nm of Al II. Special attention has been paid to the self-absorption of the spectral lines used. The measures were realized with different delay times after the pulse of the laser (1-8 (is) and with a time window of 1 (is. In LSP the electron density obtained was between 10 17 cnr 3 for the shortest delays (4-6 (is), and 10 1G cnr 3 for the greatest delays (7,8 (is).