Here, we demonstrate that high magnetic fields alter
the wettability
of water and ionic solutions on the single-crystal α-Al2O3. We investigated the relationship between the
substrate crystal orientation, material magnetism, liquid conductivity,
and the surface contact angle. Applying high magnetic fields decreased
the water contact angles on all of the surface orientations studied,
and the reduction was larger for more magnetic substrates. For ionic
solutions, high magnetic fields increased the contact angle on the
(0001) α-Al2O3 surface but decreased the
contact angles on the (11
0), (1010), and (0112) surfaces. We attribute these orientation-dependent ionic solution
responses to competition between the field-induced sample magnetization
energy and the Lorentz force acting on the ionic solution. Overall,
this work provides new magnetic-field-based strategies for changing
the wettability and provides guidelines for fabricating novel microfluidic
systems or biointerfaces with in situ magnetic control.