2015): Magnetic-field dependence of nucleation undercoolings in non-magnetic metallic melts, Philosophical Magazine Letters,The nucleation undercoolings of non-magnetic metals like paramagnetic aluminium in high magnetic fields were measured by the differential thermal analysis technique. It was shown that the nucleation undercooling of pure aluminium increased with increasing the magnetic field, while its melting temperature was hardly changed. Based on the model of magnetic dipoles at the interface, it is proposed that the magnetic-field-induced interfacial energy mainly contributes to the increase in undercooling. The change in undercooling in the magnetic field is calculated theoretically, which is in comparison with experimental data. Additionally, the inhibition of atom diffusion in the magnetic field plays a role in the change of undercooling.
The contact angle (CA) goniometer adaptable to a superconducting magnet was developed based on the sessile drop method. The goniometer mainly consisted of the sampling system, the supporting system, and the image acquisition system. Some improvements were taken to avoid the effects of the magnetic field (MF) on the CA measurement. As an example, the CAs of water on two substrates of silica and polymethyl methacrylate (PMMA) were measured using the goniometer. The results with and without a MF showed a good repeatability and reliability. Additionally, the MF was found to reduce the CA of water, which probably stemmed from the change of the surface tension in the MF. The CA goniometer will become an important tool which is used to study the wettability of liquids on a solid in the MF.
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