Measurements and correlations of viscosity, conductivity and density of an hydrophobic ionic liquid (Aliquat 336) mixtures with a non-associated dipolar aprotic solvent (DMC)

Chemical and homogeneity changes of a Nafion membrane surface associated to its doping with the cation of the room‐temperature ionic liquid AliquatCl

“…Membrane characteristics (given by the supplier) are as follows: membrane thickness of 51 µm, density 2000 kg/m 3 , ionic conductivity 8.3 S/m, acid capacity 0.89 meq/g and initial water content of 5 wt%. The characteristic parameters of Aliquat + , which presents a branched structure, are molecular weight, M w = 368 g/mol, and molar volume, v m = 560 cm 3 /mol, while the viscosity (at 30 °C) of the RTIL is η = 1500 m Pa · s …”

“…Membrane characteristics (given by the supplier) are as follows: membrane thickness of 51 μm, density 2000 kg/m 3 , ionic conductivity 8.3 S/m, acid capacity 0.89 meq/g and initial water content of 5 wt%. The characteristic parameters of Aliquat + , which presents a branched structure, are molecular weight, M w = 368 g/mol, and molar volume, v m = 560 cm 3 /mol [9] , while the viscosity (at 30°C) of the RTIL is η = 1500 m Pa · s. [11] Samples of the pristine membrane were immersed in the RTIL Aliquat 336 for 24 h, and doped Naf-112/Aliquat + membrane samples were obtained by H + /Aliquat + exchange mechanism, with an Aliquat + content of 0.62%, which was estimated by measuring changes in the conductivity and pH of the RTIL as it was described in detailed previously. [12] Characterization Membrane surface chemical characterization was performed by XPS analysis by using a Physical Electronics spectrometer (PHI 5700) with X-ray Mg K α radiation (300 W, 15 kV, 1253.6 eV) as the excitation source was used for high-resolution record.…”

Measurement and correlation of electrical conductivity of ionic liquid [EMIM][DCA] in propylene carbonate and γ-butyrolactone

“…To overcome the disadvantages, mixing ILs with molecular liquids (MLs) can be an effective solution, which causes a significant decrease of viscosity and a sharp increase of electrical conductivity [20][21][22][23][24][25].…”

Effect of Dimethyl Carbonate on the Dynamic Properties and Ionicities of Ionic Liquids with [MIII(hfip)4]− (M=B, Al) Anions

“…This is underlined by the results for [Pyrr 14 ][NTf 2 ]/PC mixtures; their transport and excess properties indicate structural changes depending on the molar ratio of the constituents 9. In particular, ion clusters, as depicted in Figure 2, have been found in solutions of nonpolar solvents,12c, 33 whereas other suggestions involve the disturbance of the molecular structure of both IL and molecular solvent upon mixing 12a…”