1978
DOI: 10.1088/0022-3700/11/9/013
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Measurements of relative transition probabilities and the variation of the electronic transition moment for N2C3Πu-B3Πgsecond positive system

Abstract: Accurate values of the relative transition probabilities Aupsilon ' upsilon '' for 41 bands in the N2 second positive system have been measured using single-photon counting techniques on a repetitive pulsed source. A computer code simulating the band structure, including multiplet splitting, and intensity distribution enables any band intensity to be deduced from the fractional intensity seen at the peak in the P branch (band-head). The variation of the electronic transition moment with internuclear separation… Show more

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Cited by 68 publications
(45 citation statements)
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“…Emission lines of the second positive system (SPS) of N, and the first negative system (FNS) of N l account for more than 99% of the total emission intensity. Hartmann used the relative intensities of the SPS to determine transition probabilities that appeared to be in very good agreement with those determined by other methods [14]. This fact can be taken as proof of direct excitation of the C3n,-level of N,.…”
Section: Emission Spectroscopymentioning
confidence: 57%
“…Emission lines of the second positive system (SPS) of N, and the first negative system (FNS) of N l account for more than 99% of the total emission intensity. Hartmann used the relative intensities of the SPS to determine transition probabilities that appeared to be in very good agreement with those determined by other methods [14]. This fact can be taken as proof of direct excitation of the C3n,-level of N,.…”
Section: Emission Spectroscopymentioning
confidence: 57%
“…Nonintrusive optical emission spectroscopy of the discharge is commonly used to estimate the rotational temperature of molecular species in a discharge. In this paper, nitrogen band systems were studied because they can be easily identified in nitrogen carrying plasmas [23] and extensive reference data are available in the literature [17,[24][25][26][27]. Figure 8 shows the emission spectrum of nitrogen rovibronic band systems in the wavelength range from 365 to 395 nm, in the Mach 2.85 supersonic flow.…”
Section: Spectroscopic Measurementmentioning
confidence: 99%
“…E v ′ and E J ′ are vibrational state energy and rotational state energy. The more details can be found in references 20,22,24,25 . Fig.…”
Section: Methodsmentioning
confidence: 99%