The growing interest in environmentally friendly materials
is leading
to a re-evaluation of natural fibers for industrial applications in
order to meet sustainability and low-cost objectives, especially for
thermal insulation of buildings. This paper deals with the chemical
and physical characterization of fibers extracted from seagrass (
Posidonia oceanica
) and alfa grass (
Stipa tenacissima
) for a possible substitution of
synthetic materials for thermal insulation. Hemp (
Cannabis
sativa
), a fiber broadly used, was also studied for
comparison. The parameters characterized include porosity, thermal
degradation, elemental composition, skeletal and particle density
of the fibers as well as investigation of the thermal conductivity
of fiber-based panels. Several technologies were involved in investigating
these parameters, including mercury intrusion, thermogravimetric analysis,
fluorescence spectroscopy, and fluid pycnometry. The fibers showed
a degradation temperature between 316 and 340 °C for
Posidonia
, between 292 and 326 °C for alfa, and between
300 and 336 °C for hemp fibers. A high porosity allied with a
reduced pore size was revealed for
Posidonia
(77%,
0.54 μm) compared to hemp (75%, 0.61 μm) and alfa (57%,
2.1 μm) raw fibers, leading to lower thermal conductivity values
for the nonwoven panels based on
Posidonia
(0.0356–0.0392
W/m.K) compared to alfa (0.0365–0.0397 W/m.K) and hemp (0.0387–0.0427
W/m.K). Bulk density, operating temperature, and humidity conditions
have been shown to be determining factors for the thermal performance
of the panels.