In order to increase the flexural strength and to adjust the coefficient of thermal expansion (CTE), TiO 2 was introduced into Li 2 O-Al 2 O 3 -SiO 2 (LAS) glass-ceramics to satisfy LTCC applications. The effects of TiO 2 addition on the microstructure, thermal, mechanical and electrical properties were studied. The results showed that the crystal phases were composed of Li 2 OAl 2 O 3 7.5SiO 2 (major), as well as TiO 2 and CaMgSi 2 O 6 (minor). The crystal phase TiO 2 having higher CTE value could appropriately increase the CTE value of LAS to fit the silicon and remarkably improve the flexural strength of LAS glass-ceramic with low CTE. The dielectric and insulating properties also strongly depended on the amount of TiO 2 . LAS glass-ceramic sintered at 800°C with high performances was achieved in the case of 1 wt% TiO 2 : a = 2.56 9 10 -6 /°C, r = 151 MPa, e = 6.8, tand = 1.731 9 10 -3 , q = 8.29 9 10 10 X cm.