Inspired by crystal structures of the diamond and polymer/ceramic core-shell structures of hard biological materials, diamond-structured polymer/SiN microlattices with enhanced mechanical properties have been fabricated by 3D printing and plasma enhanced chemical vapor deposition method. It is found that the compressive strength of the resultant microlattices improves with increasing silicon nitride film thickness and can reach 1.95 MPa at the thickness of 400 nm, which is 3.4 times higher than the pure polymer, but a little increase of 4.8% in density, which is only 169.2 kg m À3 . The work may provide a simplified and feasible avenue to improve the strength of low density materials.Lightweight cellular materials have wide applications in fields of aerospace, transportation, and architecture, due to their unique properties such as acoustic absorption, [1,2] energy absorption, [3] thermal insulation, [4] and shock or vibration damping. [5] Human have created numerous lightweight cellular materials, including honeycombs, [6,7] aerogels, [8][9][10] foams, [11][12][13][14][15] microlattices. [16] Microlattices are a new class of cellular materials possessing lower density and better mechanical performance than traditional random foams, because of the order and periodicity in structure. There have been many studies on microlattices with different constituent, like polymer, [17,18] metal, [19][20][21] ceramic, [22][23][24][25] and graphene. [26] The structure of lattices is formed by repeating a unit cell with specific geometry periodically in three dimensions, so, the density and mechanical performance of the lattices depend strongly on the cell geometry including shape, size, and structural hierarchy. [27][28][29] Among common topologies used to produce structure materials, the diamond structure is preferred for attaining high strength and lower density materials for its special configuration, which exhibits high spatial symmetry and strong stability to resist deformation. [30][31][32] The strength of lattice materials is determined not only by the architecture but also by the constituent materials. Among numerous engineering materials, ceramics have the highest strength and stiffness. Furthermore, silicon nitride is one of the materials with highest hardness in nature, which belongs to atomic crystal. However, ceramics are limited for applications because of their brittleness. During the process of hundreds of million years of evolution, nature has already developed the ability to turn brittleness into toughness by combining ceramic and organic matter into hybrid composites, which exhibit much enhanced strength in comparison to their constituents. [33,34] Examples include wood, [1] bone, [35,36] sponge, [37] nacre, [38] crustaceans, and exoskeleton of arthropods. [39,40] As a typical example, crustacean cuticle was formed from a chitin-protein organic template, mineralized by calcium phosphate and calcium carbonate, resulting a composite structure comprised of organic core and inorganic shell, whose stiffness (>5 G...