1964
DOI: 10.1021/ja01058a020
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Mechanism of the Formation of Di-t-butylnitroxide from t-Nitrobutane and Sodium Metal

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Cited by 122 publications
(35 citation statements)
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“…DTBN was prepared by Dr. K. Ogan (17) by the method of Hoffman et al (18). The fraction used was 90% pure.…”
Section: Methodsmentioning
confidence: 99%
“…DTBN was prepared by Dr. K. Ogan (17) by the method of Hoffman et al (18). The fraction used was 90% pure.…”
Section: Methodsmentioning
confidence: 99%
“…Nuclear hyperfine splitting constants and spinadduct concentration were determined by comparison of the unknown spin adduct to a spectrophotometrically standardized solution of di-tert-butyl nitroxide (Xmx 465 nm, e = 8.9L/cm-1 mole) (16).…”
Section: Esr Measurementsmentioning
confidence: 99%
“…However, it is known to be formed in the reactions of t-BuNO-, with sodiunz metal (20) or with organo-alkali co~npounds (21) and also in its electrochemical reduction (22). These all involve thc radical anion of t-BLINO-, which is assumed to bc unstable leacling t o the formkltion of 8.…”
mentioning
confidence: 99%