2021
DOI: 10.1016/j.jorganchem.2021.121888
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Mechanistic exploration of Rh(III)-catalyzed C-H allylation of benzamides with allyl bromide

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“…In recent years salicylaldehydes have been widely used as an important key-structural motif for the generation of various significant organic scaffolds such as chromones, benzofurans, chroman-4-ones, homoisoflavonoids and flavones by directed aldehydic C-H activation. [28][29][30][31][32][33][34][35] Chromones are the oxygen-containing heterocycles which are frequently found in biologically significant natural products such as flavones and isoflavones. Hitherto, a lot of transition-metal catalysed C-H activations of salicylaldehydes have been reported, but only one Ir-catalysed C-H activation of salicylaldehyde has been reported, by Miura and coworkers.…”
Section: Introductionmentioning
confidence: 99%
“…In recent years salicylaldehydes have been widely used as an important key-structural motif for the generation of various significant organic scaffolds such as chromones, benzofurans, chroman-4-ones, homoisoflavonoids and flavones by directed aldehydic C-H activation. [28][29][30][31][32][33][34][35] Chromones are the oxygen-containing heterocycles which are frequently found in biologically significant natural products such as flavones and isoflavones. Hitherto, a lot of transition-metal catalysed C-H activations of salicylaldehydes have been reported, but only one Ir-catalysed C-H activation of salicylaldehyde has been reported, by Miura and coworkers.…”
Section: Introductionmentioning
confidence: 99%