Mechanistic study of [RuCl3(H2O)2OH]− catalyzed oxidation of l-leucine by acidic N-bromophthalimide

Jain, Bhawana; Singh, Ajaya Kumar; Negi, Reena

doi:10.1007/s13738-015-0646-4

J IRAN CHEM SOC

2015

DOI: 10.1007/s13738-015-0646-4

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Mechanistic study of [RuCl3(H2O)2OH]− catalyzed oxidation of l-leucine by acidic N-bromophthalimide

Bhawana Jain¹,

Ajaya Kumar Singh²,

Reena Negi³

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Cited by 3 publications

References 28 publications

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Oxidative behavior of N-bromophthalimide for organic compounds: a review

Jain¹,

Negi

Singh³

2018

SN Appl. Sci.

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Organic compounds receive from industries as effluents are highly toxic and hazardous for the environment. Conventional oxidation process for the oxidation of organic compounds through use of N-bromophthalimide (NBP) is one of the significant process for conversion of organic compounds into environmental friendly or less harmful substances. The main scenario of this review is oxidation and kinetics of different organic compounds by NBP with different experimental methods-iodometric and potentiometric along with uncatalyzed, and catalyzed system. In addition to this we also summarize synthesis, properties and reactive species of NBP. Oxidation products obtained by oxidation of various organic compounds by NBP were acetic acid, aldehyde, carbon dioxide, ammonia, cyanide, aldonic acid etc. Present review, first time offers all aspects of NBP as an oxidizing agent for oxidation of organic compounds.

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Oxidative behavior of N-bromophthalimide for organic compounds: a review

Jain¹,

Negi

Singh³

2018

SN Appl. Sci.

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Kinetics and mechanistic study of oxidation of paracetamol: an accelerated catalytic approach

Negi

Jain²,

Singh³

et al. 2019

SN Appl. Sci.

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In the present paper, a simple, and novel method for the abatement of paracetamol (PA) in aqueous system into environmental friendly compound benzoquinone at 308 K has been described, and was accelerated by simple, and inexpensive catalyst Cu(II)/Ni(II). A comparative assessment between Cu(II) and Ni(II)catalyzed, abatement of PA by CAT was performed. It has been determined that there are very little change in rate of reaction for both Cu(II)/Ni(II) catalyzed degradation of PA. All the kinetics parameters, i.e. the effect of change in concentrations of chloramine-T (CAT), sodium hydroxide, paracetamol, catalyst, added p-toluenesulfonamide, electrolyte etc. have been studied, and measured carefully. Reaction had been studied in the range of temperature 303-323 K. On the basis of kinetic data obtained a satisfactory mechanism has been proposed. And it was deduced that, presently used process was a tenable technique for the degradation of PA. Main abatement product was confirmed by GC-MS analysis technique.

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Ru(III) catalysed oxidation of 2-propanol by Cr(VI) in micellar media

Chowdhury

Rakshit

Acharjee

et al. 2019

Journal of Molecular Liquids

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Mechanistic study of [RuCl3(H2O)2OH]− catalyzed oxidation of l-leucine by acidic N-bromophthalimide

Cited by 3 publications

References 28 publications

Oxidative behavior of N-bromophthalimide for organic compounds: a review

Oxidative behavior of N-bromophthalimide for organic compounds: a review

Kinetics and mechanistic study of oxidation of paracetamol: an accelerated catalytic approach

Ru(III) catalysed oxidation of 2-propanol by Cr(VI) in micellar media

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