Mechanistic study on NO reduction by sludge reburning in a pilot scale cement precalciner with different CO₂ concentrations

Abstract

An experimental study on the effects of CO 2 concentration on the release of reducing gases and the NO reduction efficiency by sludge reburning was carried out in a pilot scale cement precalciner. The results indicate that sludge reburning shows an ideal NO reduction activity. The best NO reduction efficiency of 54% is reached when the CO 2 concentration is 25 vol%. Characteristic analysis of the sludge shows that the main types of reducing gases generated by sludge reburning are HCN, NH 3 , CO and CH 4 . Among them, CO 2 concentration plays a crucial role in the release of HCN, CO and CH 4 . The mechanistic study indicates that NO reduction is dominated by homogeneous reduction during the sludge reburning process, in particular the reducing gases of CO and NH 3 have significant influences on the NO reduction. Meanwhile, the effect of CO 2 concentration on NO reduction is mainly due to the difference in CO release. The results of the present study not only provide insight into the mechanism of NO reduction by sludge reburning, but could also contribute to the development of NO X removal technology in the cement industry.

Effects of co-disposal of sludge based on TTF-type precalciner on NOx emissions

“…Fang et al [11] found that combustion temperature, gas flow rate, and oxygen concentration also had significant effects on NOx removal. Xiao et al [12] conducted an experimental study on the effect of CO2 concentration on NO reduction efficiency by sludge reignition in a cement decomposer. When the CO2 concentration was 25 vol.…”

The influence of organic components in sludge on selective non-catalytic reduction denitrification

“…This processing method not only reduced the production cost of the cement (Huang et al 2018), but also the whole process is harmless, reduced and resource-based. Some scholars found that the co-disposal of sludge in cement kilns is beneficial to reduce the NOx in the kilns (Fang et al 2019;Xiao et al 2019). There are various such compounds released during the sludge pyrolysis process, as hydrocarbon, CO, HCN and NH 3 (Tang et al 2018).…”