“…As we mentioned before, we have simulated only 10 ps of the life of the system, whereas 1 μs is the time scale of the experiment. Literature sources provide some more details on the value of the force versus time scale for different types of bonds. , Although there is no Ag–C type of bond mentioned in the reference, we may assume that the trend will be continued, and we could expect the force to be lowered by approximately 15–25%. This value is even closer to the experiment, despite the simplifications used in our model such as the shorter aliphatic chains at the N1 position of the NHC ligands and absence of the solvent.…”