Mechanochemical syntheses of inorganic compounds in neutralization reactions

Polymorphism in the family of Ln6−xMoO12−δ(Ln = La, Gd–Lu; x = 0, 0.5) oxygen ion- and proton-conducting materials

“…ensures mechanochemical synthesis of mixed oxides. 24,25 Since a number of zirconium-doped rare-earth molybdates, Ln 5.4 Zr 0.6 MoO 12.3 (Ln ¼ Nd, Sm, Dy) and La 5.8 Zr 0.2 MoO 12.1 , were shown to possess oxygen ion and proton conductivity, 10,11 the total conductivity of some polymorphs of undoped Ln 6Àx -MoO 12Àd (Ln ¼ La, Yb; x ¼ 0, 0.5) was also measured in dry and wet air.…”

Mechanochemical Activation of (SeO2+Na2CO3) Mixture and Sodium Selenite Synthesis in Vibrational Mill

“…Based on the results of our previous research (19), it is justified to assume that mechanically activated chemical substances will also react with each other in the solid phase during mechanical activation of binary systems of the type: acid anhydride#alcaline carbonate. So far, mechanochemical synthesis of this type of reacting components has not been investigated.…”