Mechanochemical synthesis of N-doped porous carbon at room temperature

Abstract

One-pot mechanochemical synthesis of N-doped porous carbons at room temperature using a planetary ball mill.

Improved Electrochemical Performance of FeF3 by Inlaying in a Nitrogen‐Doped Carbon Matrix

“…These results demonstrate that compared to bare FeF 3 , the electrodes combined FeF 3 and carbon had high electron conductivity and rapid charge transfer reaction for Li + insertion/extraction. [2,85] Compared to the reported value, [4,27] the charge transfer resistance was significantly reduced to by introducing N-doped carbon matrix. After 200 cycles, the Rs and Rct values for three samples have changed obviously.…”

“…[2,85] Compared to the reported value, [4,27] the charge transfer resistance was significantly reduced to by introducing N-doped carbon matrix. These results demonstrate that compared to bare FeF 3 , the electrodes combined FeF 3 and carbon had high electron conductivity and rapid charge transfer reaction for Li + insertion/extraction.…”

Sustainable and rapid preparation of nanosized Fe/Ni-pentlandite particles by mechanochemistry

“…In order to understand the processes in the milling vessel, we monitored the temperature and pressure changes during the mechanochemical reaction for 30 minutes of milling. The investigated element samples show the reaction prole of a mechanochemically induced self-sustaining reaction (MSR) [34][35][36][37][38][39] (Fig. 4A, S16A-C †).…”

Mechanochemical Preparation of Pd(II) and Pt(II) Composites with Carbonaceous Materials and Their Application in the Suzuki-Miyaura Reaction at Several Energy Inputs

“…However, in many cases the heterogenization decreases the overall catalytic efficiency, being also expensive and difficult to achieve on industrial scale. Therefore, elaboration of simple, scalable, eco-friendly and fast technics to prepare highly active and reusable dispersed catalysts for the SM reaction constitutes a significant challenge [5][6][7], and mechanochemical methods can eventually provide an effective solution [8][9][10][11][12].…”

“…The mechanochemical preparative technics involve chemical and physico-chemical transformations of substances produced by the effect of mechanical energy. These include influencing reactivity of solids by the presence of solid-state defects, interphase interactions and relaxations, which can enable time-convenient one-step syntheses of new nanomaterials with the desired properties in a reproducible way with high yields and under simple and easy operating conditions [8][9][10][11][12]. Due to these and other phenomena (e.g., formation of "hot spots" or mechanically stimulated phase transformations) [8], many mechanochemical processes take place under environmentally friendly and essentially waste-free conditions.…”