1997
DOI: 10.1149/1.1837616
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Megasonic Excited Ozonized Water for the Cleaning of Silicon Surfaces

Abstract: Conditions to remove contaminations adsorbed on a surface in wet cleaning processes have to be perfectly controlled. Megasonic excitation of ozonized water removes hydrocarbon contamination from silicon surfaces. When ozonized water was excited by megasonics at a frequency of about 1 MHz, OH radicals were produced in the cleaning solution. As a result, we have shown that hydrocarbons on the wafer surface were oxidized by OH radicals, leading to hydrocarbon-free Si surfaces.

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Cited by 33 publications
(18 citation statements)
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“…New improvements are continually initiated aiming at a better cleaning efficiency, a lower cost, and a strict control of the environmental regulations [3,4]. After removal of the native oxide with a HF treatment, the resulting hydrophobic surface covered with Si-H x terminal bonds is successively treated in an alkaline ammonia + hydrogen peroxide mixture called SC1, to oxidize the inorganic contaminants and generate a thin chemical oxide layer, surrounding both the particles and the substrate surface.…”
Section: Introductionmentioning
confidence: 99%
“…New improvements are continually initiated aiming at a better cleaning efficiency, a lower cost, and a strict control of the environmental regulations [3,4]. After removal of the native oxide with a HF treatment, the resulting hydrophobic surface covered with Si-H x terminal bonds is successively treated in an alkaline ammonia + hydrogen peroxide mixture called SC1, to oxidize the inorganic contaminants and generate a thin chemical oxide layer, surrounding both the particles and the substrate surface.…”
Section: Introductionmentioning
confidence: 99%
“…최근에는 실리 콘 웨이퍼의 구경이 대구경화 됨에 따라 세정 횟수가 증 가하였으며 세정 과정에 사용되는 세정액 양 또한 증가 함에 소자 생산 원가가 증가하게 되며, 세정 공정에 사 용된 세정액 처리 비용 또한 증가하게 되어 효과적인 세 정액 선정이 필요한 상황이다. [4][5] 일반적인 습식 방법으 로 현재 반도체 공정에서 RCA 세정법 [6][7] 과 Dilute HF (DHF), 8) Buffered Oxide Etching(BOE)…”
Section: 서 론unclassified
“…The silicon wafer surface is cleaned following wet processes using ultrapure water, various chemical reagents, and very often megasonic wave (1)(2)(3)(4)(5)(6)(7)(8)(9)(10), Additionally, microbubbles generated by the megasonic wave have been used for various cleaning techniques (11,12). Thus, the method and conditions for its effective use have been studied by many researchers (6,9,10,13,14) based on the particle level evaluation of cleaned silicon wafer surface.…”
Section: Introductionmentioning
confidence: 99%