The developing coal-gasification technologies generate gaseous process streams laden with water-soluble species such as H2S, NH3, HCN, phenols, cresols, etc. The primary raw-gas cleanup, sometimes referred to as gas quenching, is the source of large volumes of highly contaminated wastewaters [I-31, to be encountered in coal-gasification processes. The compositions of coal-gasification wastewaters consist of high concentrations of ammonia, sulfides, alkalinity (CO,), phenol, and cresol, and moderate to low concentrations of cyanide, thiocyanate, dihydric phenols, polycyclic hydroxy and nitrogen aromatic compounds, and a large number of other toxic organics.The proposed treatment processes appear to be based largely on current practices in the coking industry and petroleum refining. The treated water can be reused as slagor ash-quench water, gas quenching, cooling tower makeup water, or boiler feedwater. T h e minimum freshwater intake for some coal-conversion plants is the sum of the evaporation losses from cooling towers, vent steam ponds, etc., and the difference in hydrogen content of the plant's products and the raw coal.The development of a membrane separation process for the removal of selected organics, salts, and scale-forming compounds from stripped (after H2S and NH, removal) coal-conversion process wastewaters, will minimize surface-water pollution and decrease water consumption by permeate recycling. The recent industrial development of noncellulosic thin-film composite membranes by using an in-situ interfacial polymerization technique has provided membranes with high salt and low molecular weight organic separation (even at a 15 x 10'to 20 X 105N/m2pressure range) characteristics and insignificant compaction problems. The low-pressure membranes (used for brackish water) have definite advantages in terms of energy savings, and lower capital cost [4]. The composite membranes perform better than cellulose-acetate membranes [5, 61.The overall objective ofthis investigation is to provide a critical evaluation of the current information concerning coal-gasification wastewaters and to establish experimentally the extent of separation of phenolics and polynuclear aromatic hydrocarbons (from single and multi-solute synthetic systems) by low-and high-pressure composite membranes. The compounds selected for experimental investigation were: phenol, 0-cresol, 2,3-dimethylphenol, catechol, resorcinol, 2-naphthol, naphthalene, and indole. The separation characteristics were evaluated under insignificant concentration polarization conditions. Membrane experiments with actual coal-conversion wastes utilizing hollow-fiber and s iral-wound modules Fuels, Inc., and IMMR) and the results will be published in a future article. are in progress (project sponsored g y Ashland Synthetic