Charge trapping flash memory devices with the structure of [TiN/W]/Al 2 O 3 /(HfO 2 ) 0.9 (Al 2 O 3 ) 0.1 /Al 2 O 3 /Si were fabricated, and their memory properties were characterized. High-κ (HfO 2 ) 0.9 (Al 2 O 3 ) 0.1 composite (named as HfAlO in short) was prepared as the charge trapping layer, and the effect of post deposition annealing (PDA) conditions on its charge trapping characteristics was also investigated. The sample treated by high PDA temperature (1000 • C) exhibits larger memory window, faster program/erase (P/E) speed, lower P/E voltage, better data retention and endurance performance, which should be ascribed to the intensive mixing of HfO 2 and Al 2 O 3 in the charge trapping layer. Therefore, the proposed memory devices show great potential in future nanoscale memory applications.