Mercaptobenzothiazole-functionalized magnetic carbon nanospheres of type Fe3O4@SiO2@C for the preconcentration of nickel, copper and lead prior to their determination by ICP-MS

Habila, Mohamed A.; ALOthman, Zeid A.; El‐Toni, Ahmed Mohamed; Labis, Joselito P.; Li, Xiaomin; Zhang, Fan; Soylak, Mustafa

doi:10.1007/s00604-016-1880-x

Cited by 45 publications

(11 citation statements)

References 44 publications

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“…In particular, the adsorbents and other relevant materials can be recycled, significantly reduced the cost for the wastewater treatment. Traditional adsorbents, such as chitosan/natural zeolites, activated carbon, and silica microspheres, have been generally used in the water treatment by wastewater industries [23]. Those materials are normally applicable for the dyes or heavy metal pollution at low concentrations because their insufficient adsorption capacity.…”

Section: Accepted Manuscriptmentioning

confidence: 99%

Magnetic metal organic frameworks (MOFs) composite for removal of lead and malachite green in wastewater

Shi

Han

et al. 2018

Colloids and Surfaces A: Physicochemical and Engineering Aspect

214

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We designed and synthesized a magnetic metal organic frameworks (MOFs) composite, Cu-MOFs/Fe3O4 as the adsorbent for removal of lead (Pb(II)) and malachite green (MG) in wastewater. This Cu-MOFs/Fe3O4 can be easily prepared by in-situ growth of Cu-MOFs with doping Fe3O4 nanoparticles. The prepared Cu-MOFs/Fe3O4 composite was well characterized by SEM, XRD, and FTIR spectra. The adsorption experiments found that Cu-MOFs/Fe3O4 can serve as adsorbent for removal of Pb(II) and MG simultaneously. The adsorption capacities were found to be 113.67mg/g for MG and 219.00 mg/g for Pb 2+ , respectively, which are significantly higher than reported materials. Adsorption isotherm, kinetics and recyclability of Cu-MOFs/Fe3O4 for removal of Pb(II) and MG were then studied. Adsorption of Pb(II) and MG exhibited Freundlich adsorption isotherm model, with the adsorption kinetics of available second-order kinetic. Physical adsorption for MG and chemical adsorption for Pb(II) were confirmed by Dubinin-Radushkevich (D-R) isothermal adsorption model. The adsorption of Pb(II) and MG in real water samples were then studied. The Fe3O4/Cu-MOFs was found to be recyclable for removal of Pb(II) and MG, can be explored as the potential adsorbent for waste water treatment.

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Section: Accepted Manuscriptmentioning

confidence: 99%

Magnetic metal organic frameworks (MOFs) composite for removal of lead and malachite green in wastewater

Shi

Han

et al. 2018

Colloids and Surfaces A: Physicochemical and Engineering Aspect

214

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“…The BET surface area for nitrogen adsorption/desorption was determined to be around 4.9462 m 2 /g. Although the fabricated adsorbent has a relatively low surface area, the presence of groups containing electronegative atoms such as O, S and P enhances the tendency for heavy metal adsorption and enables real application for extraction purposes [33,34]. The X-ray diffraction to characterize the structural nature of the prepared biomassderived adsorbent was performed, and peaks are shown in Figure 3.…”

Section: Characteristics Of the Biomass-derived Adsorbentmentioning

confidence: 99%

Biomass-Derived Adsorbent for Dispersive Solid-Phase Extraction of Cr(III), Fe(III), Co(II) and Ni(II) from Food Samples Prior to ICP-MS Detection

et al. 2021

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A biomass-derived adsorbent was simply prepared and applied as efficient and low-cost solid-phase supports. The adsorbent material was characterized by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), surface area analysis and Fourier transform infrared (FTIR) spectroscopy. The amorphous structure of the prepared adsorbent was indicated from the XRD. The prepared adsorbent exhibited surface functional groups such as carbonyl and hydroxyl groups, which enhance the application of DSPE. An accurate separation and preconcentration of Cr(III), Fe(III), Co(II) and Ni(II) prior to ICP-MS detection was achieved using the biomass-derived adsorbent. The extraction process was performed at pH 4 using 1 mL of 0.5 N nitric acid for elution and recovery of ions. The prepared biomass-derived adsorbent showed efficient performance for extraction application, exhibiting a preconcentration factor of 50 and LODs of 1.4, 2.4, 1.9 and 3.0 µg.L−1 for Cr(III), Fe(III), Co(II) and Ni(II), respectively, while the LOQs were reported as 4.1, 7.3, 5.7 and 8.9 µg.L−1 for Cr(III), Fe(III), Co(II) and Ni(II), respectively. The DSPE procedure presented was successfully applied to the determination of the Cr(III), Fe(III), Co(II) and Ni(II) contamination in some food samples.

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“…If excessive amounts of Cu 2+ accumulate in the human body, it will cause a high blood pressure, atherosclerosis, cardiac disease, etc. 15 Reported methods for detecting Cu 2+ include uorescence spectroscopy, [16][17][18][19][20][21] ICP-MS, 22 ICP-OES, 23 ame atomic absorption spectrometry, 24 the colorimetric method, 25 ion chromatography, 26 the electrochemical analysis method, 27 the CL method, [28][29][30][31] etc. Among these methods, the CL method is more sensitive, less time-consuming and easier to operate, which has great advantages in the ultra-trace analysis of Cu 2+ in a large number of samples.…”

Section: Introductionmentioning

confidence: 99%

A peroxyoxalate chemiluminescence recovery system based on the interaction of N-doped graphene oxide nanosheets and an oligopeptide for ultra-sensitive and selective copper(ii) ion detection

2022

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Mercaptobenzothiazole-functionalized magnetic carbon nanospheres of type Fe3O4@SiO2@C for the preconcentration of nickel, copper and lead prior to their determination by ICP-MS

Cited by 45 publications

References 44 publications

Magnetic metal organic frameworks (MOFs) composite for removal of lead and malachite green in wastewater

Magnetic metal organic frameworks (MOFs) composite for removal of lead and malachite green in wastewater

Biomass-Derived Adsorbent for Dispersive Solid-Phase Extraction of Cr(III), Fe(III), Co(II) and Ni(II) from Food Samples Prior to ICP-MS Detection

A peroxyoxalate chemiluminescence recovery system based on the interaction of N-doped graphene oxide nanosheets and an oligopeptide for ultra-sensitive and selective copper(ii) ion detection

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